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Reference type: Book Chapter
Authors: Sasaki DY, Rush DJ, Daitch CE, Alam TM, Assink RA, Ashley CS, Brinker CJ, Shea KJ
Publication date: 1998
Chapter title: Molecular imprinted receptors in sol-gel materials for aqueous phase recognition of phosphates and phosphonates.
Chapter number: 22
Page numbers: 314-323.
DOI: 10.1021/bk-1998-0703.ch022 Alternative URL: http://www.researchgate.net/profile/Darryl_Sasaki/publication/280895475_Molecular_Imprinted_Receptors_in_Sol-Gel_Materials_for_Aqueous_Phase_Recognition_of_Phosphates_and_Phosphonates/links/55e8aa3608aeb65162631b4f.pdf

Book title: Molecular and Ionic Recognition with Imprinted Polymers
Editors: Bartsch RA, Maeda M
Publisher: The American Chemical Society
City: Washington DC
Series title: ACS Symposium Series
Volume number: 703

Abstract: Research in our laboratory has been focused on the development of molecularly imprinted polymers (MIPs) which exhibit selectivites for various biologically active molecules. In an effort to create steroid-selective sensors we have thoroughly investigated the effect of various polymerization conditions on the selectivity of MIPs for testosterone. Separation factors (a) ranging from 3 to 10 were observed for a suite of similar steroids. Furthermore, we report a novel post-polymerization technique by which the selectivity of this type of MIP may be further enhanced. Diastereoselective recognition of peptide derivatives has also been achieved using a novel polymerizable valine derivative as a functional monomer. We have also developed an FIA-based sensor for the antibiotic chloramphenicol which relies upon the displacement of a chloramphenicoldye conjugate from an MIP by the drug. The sensor is effective over a wide range of concentrations encompassing the therapeutic dosage.


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