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Reference type: Journal
Authors: Zhang ZH, Chen X, Rao W, Chen HJ, Cai R
Article Title: Synthesis and properties of magnetic molecularly imprinted polymers based on multiwalled carbon nanotubes for magnetic extraction of bisphenol A from water.
Publication date: 2014
Journal: Journal of Chromatography B
Volume: 965
Page numbers: 190-196.
DOI: 10.1016/j.jchromb.2014.06.031
Alternative URL: http://www.sciencedirect.com/science/article/pii/S1570023214004504

Abstract: Novel magnetic molecularly imprinted polymers based on multiwalled carbon nanotubes (MWNTs@MMIPs) with specific selectivity toward bisphenol A were synthesized using bisphenol A as the template molecule, methacrylic acid, and β-cyclodextrin as binary functional monomers and ethylene glycol dimethacrylate as the cross-linker. The MWNTs@MMIPs were characterized by Fourier transform infrared, vibrating sample magnetometer, and transmission electron microscopy. Batch mode adsorption experiment was carried out to investigate the specific adsorption equilibrium and kinetics of the MWNTs@MMIPs. The MWNTs@MMIPs exhibited good affinity with a maximum adsorption capacity of 49.26 μmol g-1 and excellent selectivity toward bisphenol A. Combined with high-performance liquid chromatography analysis, the MWNTs@MMIPs were employed to extract bisphenol A in tap water, rain water, and lake water successfully with the recoveries of 89.8-95.4, 89.9-93.4, and 87.3-94.1%, respectively
Template and target information: bisphenol A, BPA
Author keywords: Molecularly imprinted polymers, bisphenol A, Multiwalled carbon nanotubes, Magnetic, Solid-phase extraction


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