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Reference type: Journal
Authors: Duan HM, Li LL, Wang XJ, Wang YH, Li JB, Luo CN
Article Title: A sensitive and selective chemiluminescence sensor for the determination of dopamine based on silanized magnetic graphene oxide-molecularly imprinted polymer.
Publication date: 2015
Journal: Spectrochimica Acta Part A-Molecular and Biomolecular Spctroscopy
Volume: 139
Page numbers: 374-379.
DOI: 10.1016/j.saa.2014.12.051

Abstract: Based on silanized magnetic graphene oxide-molecularly imprinted polymer (Si-MG-MIP), a sensitive and selective chemiluminescence sensor for dopamine measurement was developed. Si-MG-MIP, in which silanes was introduced to improve the mass transfer, graphene oxide was employed to improve absorption capacity, Fe3O4 nanoparticles were applied for separation easily and molecularly imprinted polymer was used to improve selectivity, demonstrated the advantages of the sensor. All the composites were confirmed by SEM, TEM, XRD and FTIR. Under the optimal conditions of chemiluminescence, dopamine could be assayed in the range of 8.0-200.0 ng/mL with a correlation coefficient of linear regression of 0.9970. The detection limit was 1.5 ng/mL (3σ) and the precision for 11 replicate detections of 80.0 ng/mL dopamine was 3.4% (RSD). When the sensor was applied in determining dopamine in actual samples, recovery ranged from 94% to 110%, which revealed that the results were satisfactory
Template and target information: dopamine
Author keywords: chemiluminescence, dopamine, magnetic graphene oxide, molecularly imprinted polymer, Silanization


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