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Reference type: Journal
Authors: Qiu CX, Xing YH, Yang WM, Zhou ZP, Wang YC, Liu H, Xu WZ
Article Title: Surface molecular imprinting on hybrid SiO2-coated CdTe nanocrystals for selective optosensing of bisphenol A and its optimal design.
Publication date: 2015
Journal: Applied Surface Science
Volume: 345
Page numbers: 405-417.
DOI: 10.1016/j.apsusc.2015.03.150
Alternative URL: http://www.sciencedirect.com/science/article/pii/S0169433215007461

Abstract: Twenty molecular dynamics (MD) simulations of molecular imprinting prepolymerization systems had been performed to optimize the imprinting shell of the fluorescent sensor. The results revealed that the system with a Bisphenol A (BPA): 3-aminopropyltriethoxysilane (APTES): tetraethylorthosilicate (TEOS) mole ratio of 10:15:60 had the most stable template (T)-functional monomer (FM) cluster. Correspondingly, five kinds of imprinted and non-imprinted polymers were synthesized to assess the reliability and validity of the simulation results. Hybrid SiO2-coated CdTe NCs (HS-QD) were synthesized by a simple reflux procedure including a sol-gel reaction that resulted in the formation of a hybrid SiO2 layer with CdS-like clusters on a CdTe core. Based on the optimal component ratio of the prepolymerization system, MIP shells were anchored on the surface of HS-QD to build a fluorescent MIP sensor. A linear relationship between relative fluorescence intensity and the concentration of BPA had been obtained covering the concentration range of 0.05-10 μmol L-1 with a limit of detection of 6 nmol L-1. The feasibility of the fluorescent sensor was successfully evaluated through the analysis of BPA in river water and milk. The recoveries are above 96.31%, and the relative standard deviation (RSD) ranged from 1.55% to 2.78%
Template and target information: bisphenol A, BPA
Author keywords: Molecularly imprinted polymers, fluorescence quenching, Hybrid SiO2-coated CdTe nanocrystals, Molecular dynamics simulations, bisphenol A


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