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Reference type: Journal
Authors: Yuan ZC, Zhu YK, Lan Y, Chen DJ
Article Title: Preparation of Cu(II)-Imprinted Smart Microgels for Selective Separation of Copper Ions.
Publication date: 2015
Journal: Separation Science and Technology
Volume: 50
Issue: (10)
Page numbers: 1480-1486.
DOI: 10.1080/01496395.2014.976879

Abstract: In this study, we demonstrate a new kind of surface imprinted smart polymer by using methacrylic acid (MAA) as function monomer, attapulgite as the support material, ethylene glycol dimethacrylate (EGDMA) as a crosslinker, and 2,2'-azobisisobutyronitrile (AIBN) as initiator to prepare Cu(II)-imprinted microgels. The results showed that the prepared imprinted microgels have a high affinity for Cu2+ over Ca2+ and Mg2+, and the adsorption equilibrium data fitted Freundlich isotherm model well. In addition, Cu(II)-imprinted smart microgels had pH sensitivity to control the selection recognition property. Besides, It is suggested that the Cu(II)-imprinted microgels was a material that was efficient, low-cost, and could be reused five times with about 15% regeneration loss
Template and target information: copper ion, Cu(II)
Author keywords: Surface-imprinting technique, smart microgels, selective separation, pH-sensitive, Heavy metals

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