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Reference type: Journal
Authors: Svenson J, Andersson HS, Piletsky SA, Nicholls IA
Article Title: Spectroscopic studies of the molecular imprinting self-assembly process.
Publication date: 1998
Journal: Journal of Molecular Recognition
Volume: 11
Issue: (1-6)
Page numbers: 83-86.
DOI: 10.1002/(SICI)1099-1352(199812)11:1/6<83::AID-JMR395>3.0.CO;2-P

Abstract: A method for the rapid estimation of the extent of complex formation in molecular imprinting prepolymerization mixtures is described. By the use of a UV spectroscopy titration procedure, apparent binding constants for such self-assembly processes have been obtained. This method was used for comparison of the interactions between a dipeptide template (N-acetyl-L-phenylalaninyl-L-tryptophany methyl ester) and the functional monomer methacrylic acid, and the monomer analogues acetic acid and trifluoroacetic acid. The importance of template-monomer association during the molecular imprinting prepolymerization phase is discussed with respect to the systems studied. (C) 1998 John Wiley & Sons, Ltd


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