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Reference type: Journal
Authors: Wang XR, Li BW, You HY, Chen LX
Article Title: An Ion Imprinted Polymers Grafted Paper-based Fluorescent Sensor Based on Quantum Dots for Detection of Cu2+ Ions.
Publication date: 2015
Journal: Chinese Journal of Analytical Chemistry
Volume: 43
Issue: (10)
Page numbers: 1499-1504.
DOI: 10.1016/S1872-2040(15)60867-2
Alternative URL: http://www.sciencedirect.com/science/article/pii/S1872204015608672

Abstract: A novel highly selective fluorescent sensor was fabricated based on the microfluidic paper-based analytical device for the determination of Cu2+ in aqueous samples. The glass fiber paper was activated using HCl solution and incubated in CdTe quantum dots (QDs) solution to obtain a fluorescent substrate. The Cu2+ imprinted polymers (Cu-IIP) was synthesized using 3-aminopropyl triethoxysilane (APTES) as functional monomer and TEOS as cross-linker on the surface of the glass fiber in paper at room temperature. This fluorescent sensor was successfully applied to determine the amount of Cu2+ in aqueous samples that mainly depended on the electron transition between the CdTe quantum dots and the Cu2+ for specific recognition Cu2+. A good linearity was presented in the range of 0.032-3.2 mg L-1, and the limit of detection was achieved at 0.012 mg L-1. Satisfactory recoveries ranging from 99.9% to 122.5% were attained for spiked seawater and lake water samples with four concentration levels of Cu2+. The paper@QDs@Cu-IIP showed a good performance and significant application perspectives for rapid detection of Cu2+ by comparing with the results of inductively coupled plasma-mass spectrometry (ICP-MS)
Template and target information: copper ion, Cu(II)
Author keywords: Paper-based, Ion imprinted polymers, copper ion, CdTe Quantum dots


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