MIPs logo MIPdatabase      MIP2020 Conference logo Use this space
Custom Search
Reference type: Journal
Authors: Wulff G, Vietmeier J
Article Title: Enzyme-analogue built polymers .26. Enantioselective synthesis of amino-acids using polymers possessing chiral cavities obtained by an imprinting procedure with template molecules.
Publication date: 1989
Journal: Makromolekulare Chemie-Macromolecular Chemistry And Physics
Volume: 190
Issue: (7)
Page numbers: 1727-1735.
DOI: 10.1002/macp.1989.021900724

Abstract: The asymmetric synthesis of a-amino acids within chiral cavities of special crosslinked polymers was investigated. Chiral cavities prossessing definite shapes and specific arrangements of the functional groups were obtained by preparation of crosslinked polymers in the presence of suitable templates. Best results with an enantiomeric excess of 36% were obtained by using a polymer which was imprinted by L-DOPA. The cavities contained a salicylaldehyde and a phenylboronic acid moiety each. L-Threonine was prepared by reaction of the polymer bound anion of a salicylideneglycine nickel complex with acetaldehyde

  Eat, sleep, imprint, repeat shirt  SMI logo mug  Man of proper-tea mug in green

Molecules Special Issue call      Appeal for information


Join the Society for Molecular Imprinting
Logo of the Society for Molecular Imprinting

New items RSS feed
new items RSS feed  View latest updates

Sign-up for e-mail updates:
Choose between receiving an occasional newsletter or more frequent e-mail alerts.
Click here to go to the sign-up page.

Is your name elemental or peptidic? Enter your name and find out by clicking either of the buttons below!
Other products you may like:
view listings for MIP books on eBay:

Mickey Mouse 90th Anniversary banner