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Reference type: Journal
Authors: Yamazaki T, Yilmaz E, Mosbach K, Sode K
Article Title: Towards the use of molecularly imprinted polymers containing imidazoles and bivalent metal complexes for the detection and degradation of organophosphotriester pesticides.
Publication date: 2001
Journal: Analytica Chimica Acta
Volume: 435
Issue: (1)
Page numbers: 209-214.
DOI: 10.1016/S0003-2670(01)00933-3
Alternative URL: http://144.206.159.178/FT/38/35376/606462.pdf

Abstract: For the preparation of an enzyme mimic for phosphotriester hydrolysis, we have introduced catalytic groups in a polymer, mimicking the structure of the catalytic center of the enzyme phosphotriesterase. The polymers containing Co2+-imidazole complexes show a hydrolyric activity which was 20 times higher than polymers containing only imidazole or a solution containing only cobalt ions. Additionally, a molecularly imprinted polymer that was synthesized using a paraoxon analogue as template showed higher paraoxon hydrolysis activity than a control polymer prepared in the same way but without the template molecule. (C) 2001 Elsevier Science B.V. All rights reserved
Template and target information: paraoxon


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