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Reference type: Journal
Authors: Yoshida M, Uezu K, Goto M, Furusaki S
Article Title: Required properties for functional monomers to produce a metal template effect by a surface molecular imprinting technique.
Publication date: 1999
Journal: Macromolecules
Volume: 32
Issue: (4)
Page numbers: 1237-1243.
DOI: 10.1021/ma980472m

Abstract: sWe investigated the properties required to design functional monomers which produce an imprint effect in prepared metal-imprinted polymers. Novel organophosphorus functional monomers were synthesized, and zinc-imprinted polymers were prepared with the functional monomers by a surface molecular imprinting technique. The competitive adsorption behavior of zinc and copper ions on the surface-imprinted polymers was examined, and the template effect was characterized. A slight structural change in the functional monomers, which interact with target metal ions (zinc ions in this study), resulted in a favorable change in metal recognition by the zinc- imprinted polymers. It was found that the presence of aromatic rings and a suitable straight alkyl chain in the functional monomer in addition to a high binding affinity to the target metals renders molecular recognition on the surface of the imprinted polymers effective


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