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Reference type: Book Chapter
Authors: Yoshikawa M
Publication date: 1998
Chapter title: Molecularly imprinted polymeric membranes for optical resolution.
Chapter number: 12
Page numbers: 170-187.
DOI: 10.1021/bk-1998-0703.ch012

Book title: Molecular and Ionic Recognition with Imprinted Polymers
Editors: Bartsch RA, Maeda M
Publisher: The American Chemical Society
City: Washington DC
Series title: ACS Symposium Series
Volume number: 703

Abstract: An alternative molecular imprinting technique is used to obtain polymeric membranes for enantioselcctive separations. In this technique, the "molecular memory" of the print molecule is introduced into the membrane at the same time that the polymeric membrane is being cast from its polymer solution. We have found that a membrane which contains an oligopeptide residue from an L-amino acid and is imprinted by a L-amino acid derivative recognizes the L-isomer in preference to the corresponding D-isomer, and vice versa. By application of electrodialysis, the amino acid isomer which is preferentially adsorbed in the membrane may be transported across the membrane

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