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Reference type: Journal
Authors: Yoshikawa M, Yonetani K
Article Title: Molecularly imprinted polymeric membranes with oligopeptide tweezers for optical resolution.
Publication date: 2002
Journal: Desalination
Volume: 149
Issue: (1-3)
Page numbers: 287-292.
DOI: 10.1016/S0011-9164(02)00790-7

Abstract: Molecularly imprinted polymeric membranes were prepared from various oligopeptide tweezers by adopting Boc-D-Trp as a print molecule. Molecularly imprinted membranes recognized the D- isomer of Ac-Trp, of which absolute configuration was the same as that of the print molecule, from racemic Ac-Trp mixtures, while the control membranes hardly showed chiral recognition ability. Those membranes transported Ac-D-Trp in preference to the corresponding enantiomer by electrodialysis. Permselectivity toward the D-isomer exceeded the adsorption selectivity


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