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Reference type: Journal
Authors: Yu C, Ramström O, Mosbach K
Article Title: Enantiomeric recognition by molecularly imprinted polymers using hydrophobic interactions.
Publication date: 1997
Journal: Analytical Letters
Volume: 30
Issue: (12)
Page numbers: 2123-2140.
DOI: 10.1080/00032719708001728
Alternative URL: http://www.informaworld.com/10.1080/00032719708001728

Abstract: Molecularly imprinted polymers prepared using acrylamide as the hydrogen bonding functional monomer exhibited good enantiomeric recognition properties in aqueous solutions. Our results indicate that the recognition improved with increased mobile phase water percentage and ionic strength, and was also very much pH dependent upon the ionisation properties of the sample molecules. The results can be interpreted in terms of specific hydrophobic interactions between the enantiomeric species and the recognition sites of imprinted polymers. A study of substrate selectivity showed differences between a pure organic system and a water/organic system as the mobile phases. The hydrophobicity of the test compounds was found to be an important parameter in determining the selectivity
Template and target information: Cbz-L-Glu, Boc-L-Trp, Boc-L-Tyr, Cbz-L-Trp, Ac-L-Trp, Boc-L-Phe

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