Authors: Burgemeister T
, Grobe-Einsler R
, Grotstollen R
, Mannschreck A
, Wulff G
On the chemistry of binding-sites .1. Fast thermal breaking and formation of a B-N bond in 2-(aminomethyl)benzeneboronates.
Publication date: 1981
Journal: Chemische Berichte-Recueil
Abstract: The title compounds 1 to 6 (Table 1) are shown by 1H, 11B, and 15N NMR shifts to form an intramolecular B-N bond which, according to 1H and 13C NMR, is frequently broken ( D Gc * = 40 to 54 kJ/mol, Table 2) and re-formed
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