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Reference type: Journal
Authors: Deore B, Freund MS
Article Title: Saccharide imprinting of poly(aniline boronic acid) in the presence of fluoride.
Publication date: 2003
Journal: Analyst
Volume: 128
Issue: (6)
Page numbers: 803-806.
DOI: 10.1039/b300629h
Alternative URL: http://www.umanitoba.ca/chemistry/people/freund/pdf/journals/2003_A_128_803-806.pdf

Abstract: A new approach for the electrosynthesis of saccharide-imprinted poly(aniline boronic acid) is described. The method involves the formation of a saccharide-aminophenylboronic acid complex in the presence of fluoride to allow the electropolymerization of a self-doped, molecularly imprinted polyaniline. The formation of the anionic monomer complex enables electrochemical polymerization at near neutral pH (5-7) ensuring the incorporation of saccharide in the resulting, self-doped polymer. In this work, films were imprinted with D- fructose where saccharide-aminophenylboronic acid complexation occurred in the presence of one equivalent of fluoride. The selectivity toward D-fructose relative to D-glucose showed an increase of over 25% as a result of imprinting. In addition to the enhanced selectivity, to the best of our knowledge this is the first example of the electropolymerization of a self-doped polyaniline homopolymer under neutral pH conditions


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