Authors: Nopper D
, Lammershop O
, Wulff G
, Gauglitz G
Amidine-based molecularly imprinted polymers - new sensitive elements for chiral chemosensors.
Publication date: 2003
Journal: Analytical and Bioanalytical Chemistry
Abstract: Using the optical measurement technique reflectometric interference spectroscopy (RIfS), the interaction of molecularly imprinted polymers (imprinted with either (R,R)- or (S,S)-2,3-di-O-benzoyltartraric acid) with the corresponding templates and template antipodes were investigated. With these sensors chiral separation with a separation factor of 1.2 could be achieved whereas a reference polymer resulted in no separation. RIfS signals were of opposite sign for imprinted polymer layers containing phenylboronic acid binding site monomers
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