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Reference type: Journal
Authors: Huan SY, Chu H, Jiao CX, Zeng GM, Huang GH, Shen GL, Yu RQ
Article Title: Selective electrochemical molecular recognition of benzenediol isomers using molecularly imprinted TiO2 film electrodes.
Publication date: 2004
Journal: Analytica Chimica Acta
Volume: 506
Issue: (1)
Page numbers: 31-39.
DOI: 10.1016/j.aca.2003.10.082

Abstract: In this paper, selective recognition of benzenediol isomers was studied using molecularly imprinted TiO2 film formed on a graphitic electrode. The imprinting process was investigated in detail using IR. The electrode process for p-hydroquinone follows a ErCr mechanism. The cavities formed by p-phthalic acid have good selectivity toward p-hydroquinone among the isomers. The complex ratio between p-hydroquinone and binding sites was estimated to be 1:2 with an apparent equilibrium constant of 2.98 x 10(6) l(2) mol(-2). For o-hydroquinone and m-benzenediol, the ratio decreased to 1: 1 with an apparent equilibrium constant of 1.20 x 10(3) and 1.35 x 10(3) l mol(- 1). The apparent complexing ratio and equilibrium constants could shed some insight on the nature of isomeric selectivity of the recognition sites with respect to different isomers of benzenediol. The cavities designed by o-phthalic acid present good selectivity toward o-hydroquinone. (C) 2003 Elsevier B.V. All rights reserved


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