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Reference type: Journal
Authors: Blanco-López MC, Gutiérrez-Fernández S, Lobo-Castañón MJ, Miranda-Ordieres AJ, Tuñón-Blanco P
Article Title: Electrochemical sensing with electrodes modified with molecularly imprinted polymer films.
Publication date: 2004
Journal: Analytical and Bioanalytical Chemistry
Volume: 378
Issue: (8)
Page numbers: 1922-1928.
DOI: 10.1007/s00216-003-2330-2

Abstract: This article summarises our work on the development of voltammetric sensors based on molecularly imprinted polymers. Several recognition elements and integration strategies were used: 1.membranes electropolymerised at the electrode surface; 2.casting of polymeric membranes by drop-coating a solution of pre-formed polymer (polyphosphazene) and template in a low- boiling-point solvent on to the electrode surface; 3.preparation of composite membranes containing conductive material (graphite or carbon black), acrylic-type molecularly imprinted polymers (small particle size), and PVC as binder; and 4.in-situ polymerisation of a thin layer of acrylic imprinted polymer deposited on the electrode surface by spin coating. All the options evaluated offer the possibility of controlling electrode characteristics such as hydrophobic/hydrophilic character, permeability, or film thickness, which are essential for obtaining good sensor performance


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