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Reference type: Journal
Authors: Szumski M, Buszewski B
Article Title: Molecularly imprinted polymers: A new tool for separation of steroid isomers.
Publication date: 2004
Journal: Journal of Separation Science
Volume: 27
Issue: (10-11)
Page numbers: 837-842.
DOI: 10.1002/jssc.200401799

Abstract: Molecularly imprinted polymers hold great promise for the separation of chiral compounds. A non-covalent approach to the synthesis of MIPs relies on the presence of specific and non- specific interactions, which lead to the formation of a molecular imprint. The structural differences between 17-alpha- estradiol and 17-beta-estradiol are too small to permit their efficient separation on a MIP prepared with beta-estradiol as a template. Molecular modeling revealed the presence of only one hydrogen bond that differentiates the two isomers


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