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Reference type: Journal
Authors: Takeuchi T, Ugata S, Masuda S, Matsui J, Yane T, Takase M
Article Title: Atrazine transformation using synthetic enzymes prepared by molecular imprinting.
Publication date: 2004
Journal: Organic & Biomolecular Chemistry
Volume: 2
Issue: (18)
Page numbers: 2563-2566.
DOI: 10.1039/b407002j

Abstract: Atrazine imprinted synthetic polymers were prepared using a combination of methacrylic acid and 2-sulfoethyl methacrylate that bound and converted atrazine and other 6-chlorotriazine herbicides to less toxic compounds. A chloride at the 6- position of the triazines was converted to a methoxy group by the polymer in a methanol-containing solvent, where the imprinting effects enhanced the catalytic activity. Competitive inhibition of the atrazine methanolysis was observed in the presence of a structurally related binder, ametryn, suggesting that the catalytic reaction proceeded in the binding sites generated by the molecular imprinting process


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