Authors: Elmer SL
, Zimmerman SC
Cross-linking dendrimers with allyl ether end-groups using the ring-closing metathesis reaction.
Publication date: 2004
Journal: Journal of Organic Chemistry
Alternative URL: http://www.scs.uiuc.edu/zimmerman/downloads/92.pdf
Abstract: A third generation Frechet-type dendrimer containing 24 allyl ether end-groups was synthesized, crosslinked using the ring- closing metathesis (RCM) reaction, and the core was removed hydrolytically without significant fragmentation. The results are analogous to those previously reported for homoallyl ether dendrimers (Wendland, M. S.; Zimmerman, S. C. J. Am. Chem. Soc. 1999,121,1389-1390) suggesting that the less readily available homoallyl ether dendrimers can be replaced by their allyl ethers analogues in a range of applications
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