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Reference type: Journal
Authors: Corma A
Article Title: Attempts to fill the gap between enzymatic, homogeneous, and heterogeneous catalysis.
Publication date: 2004
Journal: Catalysis Reviews - Science and Engineering
Volume: 46
Issue: (3-4)
Page numbers: 369-417.
DOI: 10.1081/CR-200036732
Alternative URL: http://www.informaworld.com/10.1081/CR-200036732

Abstract: Bio-inspired and single site metal complex catalysts have been discussed to direct towards a rational design of solid heterogeneous catalysts. When concepts derived from catalytic antibodies, molecular imprinting and molecular recognition, and site isolation and modification by appropriate ligands are combined, with new techniques to prepare, tailor made solid materials, catalysts can be prepared that improve reaction rate and selectivity by increasing the concentration and activation of reactants in the vicinity of the active sites, and by stabilizing transition states or intermediate products. It is also shown that enzymatic, homogeneous and hetergeneous catalysts can be combined to perform "one-pot" cascade reactions
Template and target information: Review - catalyst design


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