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Reference type: Book Chapter
Authors: Asanuma H, Shibata M, Hishiya T, Komiyama M
Publication date: 1999
Chapter title: Molecularly imprinted cyclodextrin polymers as artificial receptors - The requisites for remarkable imprinting.
Page numbers: 235-238.

Book title: Proceedings of the 9th International Symposium on Cyclodextrins
Editors: Labandeira JJT, Vila-Jato JL
Publisher: Kluwer Academic Publishers
City: Dordrecht
ISBN: 0-7923-5721-3

Abstract: Polymeric receptors for cholesterol were synthesized by crosslinking cyclodextrin (beta-CyD) with hexamethylene diisocyanate or toluene 2,4diisocyanate in, dimethyl sulfoxide (DMSO) in the presence of cholesterol as the template. Non-imprinted beta-CyD polymers were much poorer in the cholesterol adsorption. Use of DMSO as the crosslinking solvent is necessary for the imprinting, since beta-CyD molecules can satisfactorily form inclusion completes with cholesterol in this solvent and thus their mutual conformation in the polymer is regulated appropriately for cholesterol binding


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