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Reference type: Conference Proceeding
Authors: Kondo F, Yamashita K, Dewa T, Nango M
Publication date: 2002
Article title: Molecular design of hydrogel catalyst for hydrolysis -Attempt to molecular imprinting in water-.
Page numbers: 1429
Alternative URL: http://www.jstage.jst.go.jp/article/spsjppj/51m/0/51m_1429/_article

Proceedings title: Polymer Preprints, Japan
Volume number: 51m

Abstract: We synthesized a thermosensitive hydrogel-catalyst, which change a conformation in response to external stimuli. We regard the hydrogel-catalyst as a model of an enzyme that recognizes a substrate and catalyzes a reaction selectively within the specific temperature range. We have reported that we could control the catalytic activity by using a thermosensitive hydrogel-catalyst possessing an imidazole group in an esterolysis of an active ester. And also we have prepared the functional hydrogel that recognized their substrate by using a coordinate bond of Cu(II) with pyridine-units. In this study, we attempt to introduce both of specificities (selectivity and responsibility) to a hydrogel-catalyst.


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