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Reference type: Conference Proceeding
Authors: Yamashita K, Kondo F, Ohashi K, Sahara M, Dewa T, Nango M
Publication date: 2002
Article title: Dependence of gel structure on the molecular recognition ability of stimuli-responsive imprinting hydrogel.
Page numbers: 1843
Alternative URL: http://www.jstage.jst.go.jp/article/spsjppj/51/0/51_1843/_article

Proceedings title: Polymer Preprints, Japan
Volume number: 51

Abstract: We prepare a stimuli-responsive imprinting hydrogel that bind Cu(II) ions selectively. We adopt the following two-step procedure to prepare the imprinting hydrogel possessing interpenetrated polymer network system. Firstly we prepare a soft hydrogel that freely change their conformation in accordance with a guest molecule, and then the hydrogel is incubated in heavy metal ion solution to bind the template ions. Secondly, the metal bound hydrogel tightly fastened with a secondary gel-network of PNIPAm in order to memorize the coordination structure. In this study we report the dependence of gel structure on the molecular recognition ability of the hydrogel.


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