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Reference type: Journal
Authors: Ghosh S, Ramakrishnan S
Article Title: Small-molecule-induced folding of a synthetic polymer.
Publication date: 2005
Journal: Angewandte Chemie International Edition
Volume: 44
Issue: (34)
Page numbers: 5441-5447.
DOI: 10.1002/anie.200501448

Abstract: Stack 'em high: A polyimide with pyromellitic diimide units linked by hexaoxyethylene segments can be made to fold by cooperative two-point interactions on addition of a folding agent (see scheme). The ammonium group of the folding agent forms complexes with the oxyethylene spacer which greatly facilitates the formation of charge-transfer complexes between the aromatic units of the two components.
Author keywords: charge transfer, crown compounds, donor-acceptor systems, polymer folding


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