MIPs logo MIPdatabase      MIP2020 Conference logo Use this space
Custom Search
Reference type: Book Chapter
Authors: Fish RH
Publication date: 1998
Chapter title: Metal ion templated polymers: Studies of N-(4-vinylbenzyl)-1,4,7-triazacyclononane-metal ion complexes and their polymerization with divinylbenzene: The importance of thermodynamic and imprinting parameters in metal ion selectivity studies of the demetallated, templated polymers.
Chapter number: 16
Page numbers: 238-250.
DOI: 10.1021/bk-1998-0703.ch016

Book title: Molecular and Ionic Recognition with Imprinted Polymers
Editors: Bartsch RA, Maeda M
Publisher: The American Chemical Society
City: Washington DC
Series title: ACS Symposium Series
Volume number: 703

Abstract: A Zn2+ templated polymer, containing a sandwich arrangement of the well known 1,4,7-triazacyclononane (TACN) ligand, was found to be highly selective toward reintroduced Cu2+ in the presence of Fe3+, Co2+, Ni2+, Zn2+, and Mn2+, after the removal of the Zn2+ ion template with 6 N HC1; while a similar Hg2+ templated TACN polymer was found to be highly selective for Hg2+ in the presence of Cd2+, Pb2+, Ag+, Cu2+, and Fe3+. The following parameters were addressed: structures of the monomers of the N-(4-vinylbenzyl)TACN-Zn2+/Hg2+ complexes; polymerization parameters; structure of the polymer TACN-template metal ion complex; and selectivity to reintroduced metal ions as a function of the thermodynamic stability and the metal ion templating parameters for the polymer TACN-metal ion complexes that are formed


  Periodic table Coach hat  PhD Scientist peptide mug  Gravity waves shirt

Molecules Special Issue call      Appeal for information






 

Join the Society for Molecular Imprinting
Logo of the Society for Molecular Imprinting

New items RSS feed
new items RSS feed  View latest updates

Sign-up for e-mail updates:
Choose between receiving an occasional newsletter or more frequent e-mail alerts.
Click here to go to the sign-up page.


Is your name elemental or peptidic? Enter your name and find out by clicking either of the buttons below!
Other products you may like:
view listings for MIP books on eBay:



Mickey Mouse 90th Anniversary banner