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Reference type: Journal
Authors: Anderson CD, Shea KJ, Rychnovsky SD
Article Title: Strategies for the generation of molecularly imprinted polymeric nitroxide catalysts.
Publication date: 2005
Journal: Organic Letters
Volume: 7
Issue: (22)
Page numbers: 4879-4882.
DOI: 10.1021/ol051749n

Abstract: Two strategies for preparing catalytically active molecularly imprinted nitroxide-containing polymers are outlined. Both strategies rely upon the thermal rearrangement chemistry of tertiary amine N-oxides. To this end, several polymers were prepared and the polymeric nitroxides were revealed by oxidation with m-CPBA. All of the resulting polymeric catalysts proved to be competent mediators of the oxidation of alcohols.


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