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Reference type: Journal
Authors: Mirsky VM, Hirsch T, Piletsky SA, Wolfbeis OS
Article Title: A spreader-bar approach to molecular architecture: formation of stable artificial chemoreceptors.
Publication date: 1999
Journal: Angewandte Chemie International Edition
Volume: 38
Issue: (8)
Page numbers: 1108-1110.
DOI: 10.1002/(SICI)1521-3773(19990419)38:8<1108::AID-ANIE1108>3.0.CO;2-C

Abstract: The destructive influence of lateral diffusion on nanostructured monolayers can be prevented by using the spreader-bar technique. This approach allows the formation of stable artificial receptors for barbituric acid by lateral structuring of a dodecanethiol monolayer with molecular spreader-bars from thiobarbituric acid without chemical polymerization (see schematic representation). The new technique may have applications in chemosensors, affinity chromatography, stereoselective catalysis, and molecular electronics


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