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Reference type: Journal
Authors: Wang CH, Li CY, Wang F, Wang CF
Article Title: Phosphonate electrochemical recognition by molecularly imprinted deposited film.
Publication date: 2006
Journal: Applied Surface Science
Volume: 253
Issue: (4)
Page numbers: 2282-2288.
DOI: 10.1016/j.apsusc.2006.04.050
Alternative URL: http://www.sciencedirect.com/science/article/B6THY-4K2SK06-4/2/b990f9cda678bc960474329fda32782d

Abstract: In this paper, thin films of titanium oxide imprinted with O,O-dimethyl-(2,4-dichlorophenoxyacetoxyl)(3'-nitrobenyl) methinephosphonate (Phi-NO2) were prepared via liquid phase deposition (LPD) method on a glassy carbon electrode. The imprinted molecular in the films was removed by treatment with immersion in CH2Cl2. X-ray diffraction (XRD) and electrochemical methods were introduced to show the evidence of the molecular imprinting phenomenon. It was also found that the recognition ability of the sensor depended on the substituents associated with tridimensional structures of the nitro-compounds. Under the optimized condition, the sensor showed better sensitivity, selectivity and reproducibility to the imprinted molecule and the linear relationship between the current and the concentration of analyte in the range of 0.1-50 μM was obtained. LPD proved to be a powerful method for imprinting titanium oxide thin sense films
Template and target information: O,O-dimethyl-(2,4-dichlorophenoxyacetoxyl)(3'-nitrobenyl) methinephosphonate, Phi-NO2
Author keywords: TiO2 thin film, Molecularly imprinted sensor, Liquid phase deposition, Phosphonate

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