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Reference type: Journal
Authors: Palaprat G, Marty JD, Routaboul C, Lattes A, Mingotaud AF, Mauzac M
Article Title: Study of Hydrogen Bonding in Liquid Crystalline Solvent by Fourier Transform Infrared Spectroscopy.
Publication date: 2006
Journal: Journal of Physical Chemistry A
Volume: 110
Issue: (47)
Page numbers: 12887-12890.
DOI: 10.1021/jp063987l

Abstract: A hydrogen-bonded complex between an aromatic acid and an enantiopure chiral amine has been dissolved in a nematic solvent, giving rise to a cholesteric medium. Fourier transform infrared (FT-IR) experiments have been performed at various temperatures on both sides of the cholesteric-isotropic transition. Liquid crystalline order provides significant enhancement to the strength of interaction, inducing a discontinuous jump in concentration of the complex at the cholesteric-isotropic transition.


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