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Reference type: Journal
Authors: Wang HJ, Zhou WH, Yin XF, Zhuang ZX, Yang HH, Wang XR
Article Title: Template Synthesized Molecularly Imprinted Polymer Nanotube Membranes for Chemical Separations.
Publication date: 2006
Journal: Journal of the American Chemical Society
Volume: 128
Issue: (50)
Page numbers: 15954-15955.
DOI: 10.1021/ja065116v

Abstract: In this report, we describe the synthesis of a molecularly imprinted polymer (MIP) nanotube membrane, using a porous anodic alumina oxide (AAO) membrane by surface-initiated atom transfer radical polymerization (ATRP). The use of a MIP nanotube membrane in chemical separations gives the advantage of high affinity and selectivity. Furthermore, because the molecular imprinting technique can be applied to different kinds of target molecules, ranging from small organic molecules to peptides and proteins, such MIP nanotube membranes will considerably broaden the application of nanotube membranes in chemical separations and sensors. This report also shows that the ATRP route is an efficient procedure for the preparation of molecularly imprinted polymers. Furthermore, the ATRP route works well in its formation of MIP nanotubes within a porous AAO membrane. The controllable nature of ATRP allows the growth of a MIP nanotube with uniform pores and adjustable thickness. Thus, using the same route, it is possible to tailor the synthesis of MIP nanotube membranes with either thicker MIP nanotubes for capacity improvement or thinner nanotubes for efficiency improvement.
Template and target information: β-estradiol

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