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Reference type: Journal
Authors: Goto H
Article Title: Electrochemical polymerization of pyrrole in cholesteric liquid crystals: Morphology and optical properties.
Publication date: 2007
Journal: Journal of Polymer Science Part A: Polymer Chemistry
Volume: 45
Issue: (8)
Page numbers: 1377-1387.
DOI: 10.1002/pola.21900

Abstract: Electrochemical polymerization in a cholesteric liquid-crystal electrolyte was carried out. Polypyrrole thus synthesized in a cholesteric liquid-crystal electrolyte could be clearly seen to form a specific morphology. The polypyrrole films exhibited chiroptical properties and formed various surface structures such as Schlieren, Nazca-line, sea-anemone, and wire-loop structures. These structures that developed during polymerization were preserved even after washing. Moreover, no chiral molecule reacted chemically with the monomer during polymerization, and the electrolyte functioned only as a matrix chiral continuum. 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1377-1387, 2007
Author keywords: chiral, conducting polymers, electrochemistry, liquid crystals, molecular imprinting


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