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Reference type: Journal
Authors: Takeda K, Uemura K, Kobayashi T
Article Title: Hybrid molecular imprinted membranes having selectivity and separation behavior to targeted indole derivatives.
Publication date: 2007
Journal: Analytica Chimica Acta
Volume: 591
Issue: (1)
Page numbers: 40-48.
DOI: 10.1016/j.aca.2007.02.017
Alternative URL: http://www.sciencedirect.com/science/article/B6TF4-4N3GFN7-1/2/94f6a909e8a29bf2e387f723dae3ff26

Abstract: Molecular imprinted membrane of indole-3-ethanol (IE) was prepared by hybridization of IE imprinted polymer powder and polysulfone (PSf) membrane. The IE imprinted polymer by covalent imprinting method was synthesized with copolymerization of indole-3-ethyl methacrylate (IEMA) and divinylbenzene (DVB). The cross-linked P(IEMA-co-DVB) was ground to be powders having less than 63 μm size and then hybridized within PSf membrane by using phase inversion process. The resultant imprinted powder showed binding capacities of 1.8, 7.2, 0 and 0 μmol g-1 for IE, indole, 8-hydroxyquinoline and pyrrole in aqueous solution, respectively, and after hybridization with the PSf membrane, the value was 46, 26, 0 and 0 μmol g-1. As a result, it was found that the IE imprinted powder alone showed non-selectively binding to the IE, but, the hybridized powder within the PSf membrane bound selectively the IE. Evidence was presented that hydrophobic interaction of the PSf matrix caused the selective and efficient binding. We also showed separation behavior of the hybrid membranes and discussed on the binding selectivity of the IE molecule. In view point of hybrid effect of the PSf membrane and the cross-linked imprinted powder, the results of the separation of these substrates were considered
Template and target information: indole-3-ethanol, IE, indole-3-ethyl methacrylate, IEMA
Author keywords: molecular imprinted polymers, Hybrid membrane, separation, permeation, adsorption

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