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Reference type: Journal
Authors: Hosoya K, Shirasu Y, Kimata K, Tanaka N
Article Title: Molecularly imprinted chiral stationary phase prepared with racemic template.
Publication date: 1998
Journal: Analytical Chemistry
Volume: 70
Issue: (5)
Page numbers: 943-945.
DOI: 10.1021/ac9707038

Abstract: The first example of molecularly imprinted chiral stationary phase prepared using a racemic template is shown. N-(3,5-Dinitrobenzoyl)- alpha-methylbenzylamine (DNB) was chirally discriminated on the molecularly imprinted stationary phase prepared using racemic DNB as the template. A chiral monomer, (S)-(-)-N-methacryloyl-1- naphthylethylamine, was utilized as the functional monomer toward the racemic template, and its chiral recognition ability was, interestingly, found to be enhanced through racemic molecular imprinting. A thermodynamic discussion briefly suggests that the observed chiral recognition ability of the racemic imprinting was proper value


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