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Reference type: Journal
Authors: Hosoya K, Yoshizako K, Sasaki H, Kimata K, Tanaka N
Article Title: Molecular recognition towards coplanar polychlorinated biphenyls based on the porogen imprinting effects of xylenes.
Publication date: 1998
Journal: Journal of Chromatography A
Volume: 828
Issue: (1-2)
Page numbers: 91-94.
DOI: 10.1016/S0021-9673(98)00591-3

Abstract: Molecularly imprinted, uniformly sized polymeric separation media were prepared using o-, m- or p-xylene as a porogenic template to investigate recognition ability towards coplanar polychlorinated biphenyls (PCBs). PCBs having chlorine atoms at meta positions of biphenyl were preferably retained on stationary phase with m-xylene as porogenic template and PCBs having chlorine atoms at para positions of biphenyl were found to be retained longer on the stationary phase imprinted by the porogenic template, p-xylene. It was found that positional relationship between substituted chlorine atoms was also important for chromatographic recognition. (C) 1998 Elsevier Science B.V. All rights reserved


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