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Reference type: Journal
Authors: Zheng MX, Li SJ, Luo X
Article Title: Rationally Designing Molecularly Imprinted Polymer Toward a High Specific Adsorbent by Using Metal as Assembled Pivot.
Publication date: 2007
Journal: Journal of Macromolecular Science, Part A
Volume: 44
Issue: (11)
Page numbers: 1187-1194.
DOI: 10.1080/10601320701561122
Alternative URL: http://www.informaworld.com/10.1080/10601320701561122

Abstract: This article presents an original work aimed at rationally designing molecularly imprinted polymer (MIP) toward a high specific adsorbent. Assembling with cobalt as the pivot, the MIP was prepared by coordinating polymerizable monomers around an inducible template. The use of pivot obviously plays a positive role on increasing the specificity of MIP, so as to adsorb more for the template and less for its analogue. Related studies indicate that these may be a result of increasing specific interaction, which makes the MIP capable of recognizing the imprint species. Further information from thermodynamic analysis reveals that the increasing specific interaction, in logic, can be due to a higher fidelity of imprint, which specifically allures the template to bind
Template and target information: Boc-L-Phe-OH
Author keywords: molecularly imprinted polymer, adsorption, metal, assembled pivot


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