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Reference type: Journal
Authors: Li SJ, Tong KJ, Zhang DN, Huang X
Article Title: Rationally Designing Active Molecularly Imprinted Polymer Toward a Highly Specific Catalyst by Using Metal as an Assembled Pivot.
Publication date: 2008
Journal: Journal of Inorganic and Organometallic Polymers and Materials
Volume: 18
Issue: (2)
Page numbers: 264-271.
DOI: 10.1007/s10904-007-9172-x

Abstract: Abstract: This article presents an original work on rationally designing molecularly imprinted polymer toward a highly specific catalyst. Creating a metallic pivot for molecular self-assembly, the imprinted material was prepared by coordinating polymerizable monomer 1-vinylimidazole around template p-nitrophenyl phosphate. The result indicates that the use of pivot plays a positive role on increasing the specificity of prepared material, so as to significantly promote the hydrolysis of p-nitrophenyl acetate and to decrease catalysis toward its analogue. Related information indicates that these could be a result of increasing the match between binding sites and the template, which makes the polymer capable of specifically recognizing the imprint species and of promoting the conversion of reactant
Author keywords: molecular imprinting, polymers, metal, specificity, self-assembly


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