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Reference type: Journal
Authors: Lin YF, Lee SM, Chen CT, Lu KH, Tai DF
Article Title: On-surface Cyclization of Tetrapeptides using Molecularly Imprinted Polymers as Non-covalent Auxiliaries.
Publication date: 2009
Journal: Journal of the Chinese Chemical Society
Volume: 56
Issue: (1)
Page numbers: 127-134.
Alternative URL: http://proj3.sinica.edu.tw/~chem/servxx6/files/paper_10898_1237447791.pdf

Abstract: Based on the fabrication of molecularly imprinted polymeric film on cellulose paper (MIFC), we have developed a robotic system for homodetic tetrapeptide cyclization. We constructed molecularly imprinted polymeric film (MIPF) on cellulose paper as the non-covalent auxiliary to assist cyclic tetrapeptide (CTP) formation. Tetrapeptides were bound by their hydrophobic interaction with MIFC. With the help of MIFC and a coupling reagent, quantitative synthesis of CTPs was achieved conveniently for various tetrapeptides. The syntheses of cyclic tetrapeptide (CTP) could also be facilitated using the MIFC induced from CTP or other tetrapeptides with partially matched sequences
Template and target information: peptides, cyclic tetrapeptides
Author keywords: peptide, molecular recognition, imprinting, macrocycles, Synthesis design

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