Authors: Hashidzume A
, Zimmerman SC
Switching the selectivity of a polyglycerol dendrimer monomolecularly imprinted with d-(-)-fructose.
Publication date: 2009
Journal: Tetrahedron Letters
Alternative URL: http://www.sciencedirect.com/science/article/B6THS-4VPM59R-B/2/cd30c24ac3c2f556e5d4c6bae8fdb10b
Abstract: A polyglycerol dendrimer monomolecularly imprinted with d-(-)-fructose (Fru) was synthesized. The dendrimer formed adducts with several monosaccharides, Fru, d-(+)-galactose, d-(+)-glucose, d-(+)-mannose, and methyl-α-d-mannopyranoside (MMan), by removal of four water molecules. The dendrimer preferred Fru in the absence of N,N,N',N'-tetramethyldiaminomethane (TMDAM), whereas it preferred MMan in the presence of TMDAM
Template and target information: d-(-)-fructose, Fru, d-(+)-galactose, d-(+)-glucose, d-(+)-mannose methyl-α-d-mannopyranoside, MMan
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