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Reference type: Journal
Authors: Saraji M, Yousefi H
Article Title: Selective solid-phase extraction of Ni(II) by an ion-imprinted polymer from water samples.
Publication date: 2009
Journal: Journal of Hazardous Materials
Volume: 167
Issue: (1-3)
Page numbers: 1152-1157.
DOI: 10.1016/j.jhazmat.2009.01.111
Alternative URL: http://www.sciencedirect.com/science/article/B6TGF-4VJBTVG-B/2/8e5f6886f0021006ef7c7acc46516dfa

Abstract: A new ion-imprinted polymer (IIP) material was synthesized by copolymerization of 4-vinylpyridine as monomer, ethyleneglycoldimethacrylate as crosslinking agent and 2,2'-azobis-sobutyronitrile as initiator in the presence of Ni-dithizone complex. The IIP was used as sorbent in a solid-phase extraction column. The effects of sampling volume, elution conditions, sample pH and sample flow rate on the extraction of Ni ions form water samples were studied. The maximum adsorption capacity and the relative selectivity coefficients of imprinted polymer for Ni(II)/Co(II), Ni(II)/Cu(II) and Ni(II)/Cd(II) were calculated. Compared with non-imprinted polymer particles, the IIP had higher selectivity for Ni(II). The relative selectivity factor (αr) values of Ni(II)/Co(II), Ni(II)/Cu(II) and Ni(II)/Cd(II) were 21.6, 54.3, and 22.7, respectively, which are greater than 1. The relative standard deviation of the five replicate determinations of Ni(II) was 3.4%. The detection limit for 150ámL of sample was 1.6áμgáL-1 using flame atomic absorption spectrometry. The developed method was successfully applied to the determination of trace nickel in water samples with satisfactory results
Template and target information: Ni(II), nickel ion
Author keywords: Ion-imprinted polymer, Solid-phase extraction, nickel ion, atomic absorption spectrometry


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