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Reference type: Journal
Authors: Bing NC, Tian Z, Chen SW, Li QH, Xu ZL
Article Title: Molecular recognition capability and synthesis of S-naproxen molecularly imprinted polymers by surface polymerization on the surface of SBA-15.
Publication date: 2009
Journal: Journal of East China University of Science and Technology
Volume: 35
Issue: (4)
Page numbers: 564-568.
Alternative URL: http://journal.ecust.edu.cn/ch/reader/view_abstract.aspx?file_no=200904014&flag=1

Abstract: Molecularly imprinted composite materials (MICMs) selective to S-naproxen were prepared on the surface of mesoporous silica sphere (SBA-15) by a surface imprinting technique with S-naproxen as the template and 4-vinylpyridine as the functional monomer. As observed .by SEM and pore structure analysis, the microspheres coated with the synthesized molecularly imprinted polymers have a uniform particle size, narrow size distribution and high specific surface area. The polymer layer on SBA-15 can be determined by SEM, XRD and FT-IR spectroscopy. Scatchard analysis shows that two kinds of recognition sites are formed on the MICMS with the apparent binding capacities of 2.504 μmol/g and 16.680 μmol/g, respectively. Based on an isothermal binding thermodynamic investigation, the absorption to template is found to be spontaneous
Template and target information: S-naproxen, naproxen
Author keywords: chiral, molecularly imprinted polymer, S-naproxen, SBA-15, surface imprinting

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