MIPs logo MIPdatabase      MIP2020 Conference logo Use this space
Custom Search
Reference type: Journal
Authors: Koh JH, Gagné MR
Article Title: The disparate roles of chiral ligands and molecularly imprinted cavities in asymmetric catalysis and chiral poisoning.
Publication date: 2002
Journal: Abstracts of Papers of the American Chemical Society
Volume: 223
Issue: (INOR)
Page numbers: 341.
Alternative URL: http://www.acs.org/portal/resources/ACS/Subportals/inorganic/sep_orlando.pdf

Abstract: Appropriately chosen metallomonomers enable BINOL-shaped cavities (both matched and mismateched) and non-chiral cavities to be associated with the (S-MeOBiphep) PtCl2 precatalyst by molecular imprinting process. Each of the three polymers contains a polymerizable P2PtCl2, distinguished only by the shape of the associated cavity. Activation of molecularly imprinted metal complexes generates Lewis acid catalysts for the glyoxylate-ene reaction. We will present the catalysis experiment demonstrating that the cavity and chiral diphosphine ligands control the stereochemistry of poisoning by chiral BINAM ligands and the selectivity of the –ene catalysis, respectively.


  mipdatabase.com logo imprinters do it in bulk shirt  Mug featuring the name Michel spelled out in the single letter amino acid code  Perpetual student shirt

Molecules Special Issue call      Appeal for information






 

Join the Society for Molecular Imprinting
Logo of the Society for Molecular Imprinting

New items RSS feed
new items RSS feed  View latest updates

Sign-up for e-mail updates:
Choose between receiving an occasional newsletter or more frequent e-mail alerts.
Click here to go to the sign-up page.


Is your name elemental or peptidic? Enter your name and find out by clicking either of the buttons below!
Other products you may like:
view listings for MIP books on eBay:



Mickey Mouse 90th Anniversary banner