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Reference type: Book Chapter
Authors: Koide Y, Shosenji H, Maeda M, Takagi M
Publication date: 1998
Chapter title: Selective adsorption of metal ions to surface-templated resins prepared by emulsion polymerization using a functional surfactant.
Chapter number: 18
Page numbers: 264-277.
DOI: 10.1021/bk-1998-0703.ch018

Book title: Molecular and Ionic Recognition with Imprinted Polymers
Editors: Bartsch RA, Maeda M
Publisher: The American Chemical Society
City: Washington DC
Series title: ACS Symposium Series
Volume number: 703

Abstract: Monomer-type surfactants which can function as a ligand, 10-(p-vinylphenyl)decanoic acid (Rac) and 2-(p-vinylbenzylamino)alkanoic acids (RnNAc), have been used as emulsifiers for the preparation of surface-templated resins. The surfactants adsorb at the oil-water interface and emulsify divinylbenzene-styrene monomers. Emulsion polymerization using a potassium persulfate initiator or by irradiation with -rays gave fine particles which were 200-300 nm in diameter. The metal-imprinted resins prepared with Rac were 1.8 times more effective than the unimprinted resins for adsorption of Cu(II) and Zn(II)-imprinted resins showed highly effective adsorption of Zn(II). Such surface-template effects were also seen for metal-imprinted resins prepared with RnNAc, but the effect was sensitive to the alkyl chain length. The R18NAc resin was the most effective. The Cu(II)/Zn(II) ratio in competitive sorption was 3.7 for the Cu(II)-imprinted resins prepared with Rac and 4.2 with R18Nac

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