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Reference type: Journal
Authors: Shiraishi Y, Suzuki T, Hirai T
Article Title: Selective photooxidation of chlorophenols with molecularly imprinted polymers containing a photosensitizer.
Publication date: 2010
Journal: New Journal of Chemistry
Volume: 34
Issue: (4)
Page numbers: 714-717.
DOI: 10.1039/b9nj00732f

Abstract: Molecularly imprinted polymers containing a photosensitizer, rose bengal (RB), were synthesized via a polymerization of methacrylic acid (MAA) as a functional monomer and chlorophenols as template molecules. The polymeric sensitizers promote selective oxidation of target chlorophenol in water with molecular oxygen under visible light irradiation ( > 530 nm). This is due to the selective attraction of the target substrate onto the molecular recognition site on the polymer followed by efficient oxidation of the substrate by a singlet oxygen produced by the photoexcited RB units located in the vicinity of the recognition site.
Template and target information: chlorophenols, o-chlorophenol, 2-chlorophenol, m-chlorophenol, 3-chlorophenol, p-chlorophenol, 4-chlorophenol


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