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Reference type: Journal
Authors: Schwarz LJ, Danylec B, Yang YZ, Harris SJ, Boysen RI, Hearn MTW
Article Title: Enrichment of (E)-Resveratrol from Peanut Byproduct with Molecularly Imprinted Polymers.
Publication date: 2011
Journal: Journal of Agricultural and Food Chemistry
Volume: 59
Issue: (8)
Page numbers: 3539-3543.
DOI: 10.1021/jf104230f

Abstract: Molecularly imprinted solid phase extraction (MISPE) has been employed to isolate and concentrate bioactive polyphenols from peanut press waste. To this end, a molecularly imprinted polymer (MIP) templated with the phytoalexin (E)-resveratrol has been prepared via self-assembly with the functional monomer 4-vinylpyridine (4VP) in a 1:3 molar ratio. Subsequent molecular interrogation of the MIP binding sites demonstrated preferential structural selectivity for (E)-resveratrol with respect to other structurally related naturally occurring compounds. This selectivity was subsequently exploited to achieve substantial sample cleanup of peanut press waste under aqueous conditions with significant enrichment of (E)-resveratrol (>60 fold) requiring minimal sample preparation
Template and target information: (E)-resveratrol, resveratrol

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