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Reference type: Journal
Authors: Bloshenko AV, Roshchin AV, Kumpanenko IV, Ivanova NA
Article Title: An analysis of absorption-desorption of volatile organic compounds by molecularly imprinted polymer films.
Publication date: 2011
Journal: Russian Journal of Physical Chemistry B, Focus on Physics
Volume: 5
Issue: (2)
Page numbers: 332-344.
DOI: 10.1134/S1990793111020187
Alternative URL: http://www.springerlink.com/content/606166p1j60031q8/

Abstract: A theoretical analysis of the experimental data on absorption (desorption) of volatile organic compounds by (from) molecularly imprinted polymer films was performed. The theoretical time dependences of the amount of absorbed analyte in a film were calculated using a system of equations with four kinetic parameters (G, K, K sur , and C eq ), which were determined by theoretically approximating the experimental data. The special features of the absorption-desorption process in a polymer film were suggested to be described using a parameter called the specificity coefficient. Specificity coefficients were determined for all the polymers and analytes studied. The specificity coefficients obtained from the chromatographing data were compared with the imprinting factors of chromatograms calculated from the experimental retention time values. An empirical linear dependence of specificity coefficients on imprinting factor values was obtained
Author keywords: Absorption, Desorption, volatile organic compounds, Molecularly imprinted polymer films


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