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Reference type: Journal
Authors: Lo HC, Chen H, Fish RH
Article Title: Synthesis of a [{mono-N-(4-vinylbenzyl)-1,4,7- triazacyclononane}(2)Hg](OTf)(2) sandwich complex, polymerization of this monomer with divinylbenzene, and Hg2+ ion selectivity studies with the demetallated resin.
Publication date: 2001
Journal: European Journal of Inorganic Chemistry
Issue: (9)
Page numbers: 2217-2220.
DOI: 10.1002/1099-0682(200109)2001:9<2217::AID-EJIC2217>3.0.CO;2-L

Abstract: We have synthesized a novel, 1,4,7-triazacyclononane (TACK)- Hg2+ sandwich monomer, [{mono-N-(4-vinylbenzyl)-1,4,7- TACN}(2)Hg](OTf)(2), which was co-polymerized with the cross- linking agent divinylbenzene to form a Hg2+-ion templated polymer that was demetallated (> 96%) with 6 N HCl, and subsequently found to be highly selective to reintroduced Hg2+ ions in competition with Cd2+, Ag+, Pb2+, Cu2+, and Fe3+ ions at pH 2, the ionic radius and the thermodynamic parameter being more critical than imprinting

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