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Reference type: Journal
Authors: Matsui J, Tamaki K, Sugimoto N
Article Title: Molecular imprinting in alcohols: utility of a pre-polymer based strategy for synthesizing stereoselective artificial receptor polymers in hydrophilic media.
Publication date: 2002
Journal: Analytica Chimica Acta
Volume: 466
Issue: (1)
Page numbers: 11-15.
DOI: 10.1016/S0003-2670(02)00519-6

Abstract: Molecular imprinting using a linear pre-polymer bearing carboxylic and 4-vinylbenzyl residues was performed in alcohols for synthesizing stereoselective polymer receptors. Chromatographic assessment of the imprinted polymers, which are obtained by cross-linking the pre-polymer in the presence of a model template (-)-cinchonidine, showed the induction of affinity and selectivity to the template species by the imprinting procedure. Comparison with the performance of an imprinted polymer prepared with a monomer mixture instead of the pre-polymer elucidated the efficacy of the linear pre- polymer for molecular imprinting in the protic solvents. (C) 2002 Elsevier Science B.V. All rights reserved


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