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Reference type: Journal
Authors: Huo PW, Lu ZY, Liu XL, Liu XL, Gao X, Pan JM, Wu D, Ying J, Li HM, Yan YS
Article Title: Preparation molecular/ions imprinted photocatalysts of La3+@POPD/TiO2/fly-ash cenospheres: Preferential photodegradation of TCs antibiotics.
Publication date: 2012
Journal: Chemical Engineering Journal
Volume: 198-199
Issue: (1)
Page numbers: 73-80.
DOI: 10.1016/j.cej.2012.05.089
Alternative URL: http://www.sciencedirect.com/science/article/pii/S1385894712006791

Abstract: The molecular/ions surface imprinted TiO2/fly-ash cenospheres photocatalyst was prepared by molecular imprinted technology with coordination compounds of La3+ and oxytetracycline as molecular template. The phase, surface structure and light absorption of as-prepared imprinted photocatalyst were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), UV-vis diffuse reflectance spectra (UV-vis DRS) and Fourier transform infrared (FT-IR), respectively. The preferentially selected degradation and activity of imprinted photocatalyst were evaluated by degradation of different antibiotic waste water. The results indicate that molecular/ions surface imprinted photocatalyst could preferentially degradate tetracycline antibiotic molecular effectively and enhance the photocatalytic activity. The degradation rate of oxytetracycline ligand molecular could reach 76% in 60 min under visible light irradiation. The relatively coefficient of selectivity degradation on oxytetracycline could reach 4.5146 compared with the ciprofloxacin
Template and target information: oxytetracycline
Author keywords: Molecular, ions imprinted, La3+@POPD, TiO2, fly-ash cenospheres, antibiotics, Photocatalysis, Selection

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